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The cooperative dynamics of the H-bond system in 2-propanol/water mixtures: Steric hindrance effects of nonpolar head group

Sato, T. ; Buchner, Richard



Abstract

We have detd. the complex dielec. spectra of 2-propanol/water mixts. employing time domain reflectometry for the entire mixing range in 0.1≤ν/GHz≤25 at 20 °C, 25 °C, and 30 °C. At the specific concns., a frequency range was expanded up to 89 GHz with the help of waveguide interferometry. The excess activation free energy, ΔGE, enthalpy, ΔHE, and entropy, ΔSE, and their partial molar quantities, ...

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