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Relation between Dielectric and Low-Frequency Raman Spectra of Hydrogen-Bond Liquids
Fukasawa, T., Sato, T., Watanabe, J., Hama, Y., Kunz, Werner
und Buchner, Richard
(2005)
Relation between Dielectric and Low-Frequency Raman Spectra of Hydrogen-Bond Liquids.
Physical Review Letters 95 (19), 197802/1-197802/4.
Veröffentlichungsdatum dieses Volltextes: 15 Mai 2012 13:12
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.24352
Zusammenfassung
We analyzed the complex dielectric and Raman spectra of hydrogen-bond liquids in the microwave to terahertz frequency range. As for water and methanol, the high-frequency component of the dielectric spectrum, i.e., the small deviation from the principal Debye relaxation, clearly corresponds to the Raman spectrum. This indicates that the cooperative relaxation, accompanied by huge polarization ...
We analyzed the complex dielectric and Raman spectra of hydrogen-bond liquids in the microwave to terahertz frequency range. As for water and methanol, the high-frequency component of the dielectric spectrum, i.e., the small deviation from the principal Debye relaxation, clearly corresponds to the Raman spectrum. This indicates that the cooperative relaxation, accompanied by huge polarization fluctuation, is virtually not Raman active, whereas the faster processes reflect common microscopic dynamics. For ethylene glycol, the shape of the Raman spectrum also resembles that of the high-frequency deviation of the dielectric spectrum, but, additionally, a weak manifestation of the cooperative relaxation arising from quadrupolar conformers is detected.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Physical Review Letters | ||||
| Verlag: | AMER PHYSICAL SOC | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | COLLEGE PK | ||||
| Band: | 95 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 19 | ||||
| Seitenbereich: | 197802/1-197802/4 | ||||
| Datum | 2005 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Chemie IV - Physikalische Chemie (Solution Chemistry) > Prof. Dr. Werner Kunz Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Chemie IV - Physikalische Chemie (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | COLLECTIVE MOTIONS; WATER; DYNAMICS; SPECTROSCOPY; RELAXATION; MIXTURES; REGION; H2O; D2O; | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-243524 | ||||
| Dokumenten-ID | 24352 |
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