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Relation between Dielectric and Low-Frequency Raman Spectra of Hydrogen-Bond Liquids

Fukasawa, T., Sato, T., Watanabe, J., Hama, Y., Kunz, Werner and Buchner, Richard (2005) Relation between Dielectric and Low-Frequency Raman Spectra of Hydrogen-Bond Liquids. Physical Review Letters 95 (19), 197802/1-197802/4.

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We analyzed the complex dielec. and Raman spectra of hydrogen-bond liqs. in the microwave to terahertz frequency range. As for water and methanol, the high-frequency component of the dielec. spectrum, i.e., the small deviation from the principal Debye relaxation, clearly corresponds to the Raman spectrum. This indicates that the cooperative relaxation, accompanied by huge polarization ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
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Keywords:dielec frequency Raman spectra hydrogen bond liq relaxation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24352
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