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Ion specific forces between charged self-assembled monolayers explained by modified DLVO theory

Lima, E. R. A. ; Boström, M. ; Biscaia, E. C. ; Tavares, F. W. ; Kunz, Werner


We recently investigated specific ion effects near a single charged self-assembled monolayer (SAM) in a salt soln. by exploiting a modified Poisson-Boltzmann equation that accounts for both water profile and ion-surface potential profiles inferred from mol. dynamics simulations. In the present contribution we extend this work to consider two charged SAMs interacting across different salt soln. ...


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