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Activity of water and osmotic coefficients of histidine derivatives in aqueous solutions at 310.15 K

Tsurko, Elena N. ; Neueder, Roland ; Kunz, Werner


From the data of vapor pressure osmometry the activity of water, osmotic coeffs., and the values of activity coeffs. of two derivs. of histidine: N-Boc-L-histidine (Boc-His-OH, m = 0.005-0.14 mol/kg-1) and N-Boc-L-histidine-Me ether (Boc-His-OMe, m = 0.005-0.05 mol/kg-1) are obtained in aq. solns. at 310.15 K. From the comparison of water activity and osmotic coeff. values it follows that ...


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