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Specific Ion Adsorption and Surface Forces in Colloid Science

Lima, E. R. A. ; Horinek, Dominik ; Netz, R. R. ; Biscaia, E. C. ; Tavares, F. W. ; Kunz, Werner ; Boström, M.


Mean-field theories that include nonelectrostatic interactions acting on ions near interfaces have been found to accommodate many exptl. obsd. ion specific effects. However, it is clear that this approach does not fully account for the liq. mol. structure and hydration effects. This is now improved by using parametrized ionic potentials deduced from recent nonprimitive model mol. dynamics (MD) ...


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