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Ultrasonic Velocities, Densities, Viscosities, Electrical Conductivities, Raman Spectra, and Molecular Dynamics Simulations of Aqueous Solutions of Mg(OAc)2 and Mg(NO3)2: Hofmeister Effects and Ion Pair Formation

Wahab, Abdul ; Mahiuddin, Sekh ; Hefter, Glenn ; Kunz, Werner ; Minofar, Babak ; Jungwirth, Pavel



Abstract

The ultrasonic velocities, densities, viscosities, and elec. conductivities of aq. solns. of magnesium nitrate and magnesium acetate have been measured from dil. to satn. concns. at 0 ≤ t/°C ≤ 50. The temp. deriv. of the isentropic compressibility, κs, became zero at 2.28 and 2.90 mol kg-1 for Mg(OAc)2 and Mg(NO3)2 solns., resp., at 25 °C. The total hydration nos. of the dissolved ions were ...

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