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Ultrasonic Velocities, Densities, Viscosities, Electrical Conductivities, Raman Spectra, and Molecular Dynamics Simulations of Aqueous Solutions of Mg(OAc)2 and Mg(NO3)2: Hofmeister Effects and Ion Pair Formation

Wahab, Abdul ; Mahiuddin, Sekh ; Hefter, Glenn ; Kunz, Werner ; Minofar, Babak ; Jungwirth, Pavel



Abstract

The ultrasonic velocities, densities, viscosities, and electrical conductivities of aqueous solutions of magnesium nitrate and magnesium acetate have been measured from dilute to saturation concentrations at 0 <= t/degrees C <= 50. The temperature derivative of the isentropic compressibility, K-s, became zero at 2.28 and 2.90 mol kg(-1) for Mg(OAc)(2) and Mg(NO3)(2) solutions, respectively, at 25 ...

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