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Hofmeister Effects in Surface Tension of Aqueous Electrolyte Solution

Boström, M. ; Kunz, Werner ; Ninham, Barry W.



Abstract

The surface tension of electrolyte solns. shows marked specific ion effects. We here show an important role for both ionic solvation energies and ionic dispersion potentials in detg. this ion sp. surface tension of salt solns. The ion self-free energy changes when an ion moves from bulk soln. into the interfacial region, with its decreasing water d. profile. We will show that the solvation ...

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