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Dielectric spectroscopy of micelle hydration and dynamics in aqueous ionic surfactant solutions

Buchner, Richard ; Baar, C. ; Fernandez, Patrick ; Schrödle, Simon ; Kunz, Werner


The dielec. relaxation of ionic surfactant solns. is discussed by comparing results for cationic (alkyltrimethylammonium halides, CnTAX) and anionic (sodium dodecylsulfate, SDS) model surfactants. A careful anal. of the spectra yields quant. information on the hydration of the formed micelles as well as on their size and on the surface diffusion of the bound counterions. The results are not ...


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