Kunz, Werner, Belloni, L., Bernard, Olivier and Ninham, Barry W. (2004) Osmotic coefficients and surface tensions of aqueous electrolyte solutions: Role of dispersion forces. Journal of Physical Chemistry B 108 (7), pp. 2398-2404.
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Abstract
Osmotic coeffs. of a series of 16 aq. electrolyte solns. are described at concns. ≤1 M with the help of HNC calcns. and solvent-averaged potentials of charged hard spheres with an addnl. necessary dispersion potential, omitted from all earlier treatments. The adjusted ionic radii and excess polarizabilities have values of the expected order of magnitude. Whereas the description of the bulk ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2004 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz | ||||
| Identification Number: |
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| Keywords: | electrolytic soln osmotic coeff surface tension calcn dispersion force | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 24599 |
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