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MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions

Papaiconomou, Nicolas ; Simonin, Jean-Pierre ; Bernard, Olivier ; Kunz, Werner



Abstract

The mean spherical approximation (MSA) approach for electrolyte solutions is combined with a modified non-random two-liquid (NRTL) approach. The resulting model is suitable for a description of the thermodynamic properties of electrolyte-multisolvent systems. The ability of this MSA-NRTL model is investigated by examining activity and osmotic coefficients of binary and ternary electrolyte ...

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