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MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions

Papaiconomou, Nicolas, Simonin, Jean-Pierre, Bernard, Olivier and Kunz, Werner (2002) MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions. Physical Chemistry Chemical Physics 4 (18), pp. 4435-4443.

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Abstract

The mean spherical approxn. (MSA) approach for electrolyte solns. is combined with a modified non-random two-liq. (NRTL) approach. The resulting model is suitable for a description of the thermodn. properties of electrolyte-multisolvent systems. The ability of this MSA-NRTL model is investigated by examg. activity and osmotic coeffs. of binary and ternary electrolyte solns. Esp. for non-aq. solns., the model is superior to std. semi-empirical calcns. used in the chem. industry.


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Item type:Article
Date:2002
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1039/b204841hDOI
Keywords:electrolyte soln thermodn MSA NRTL model
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24615
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