Papaiconomou, Nicolas, Simonin, Jean-Pierre, Bernard, Olivier and Kunz, Werner (2002) MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions. Physical Chemistry Chemical Physics 4 (18), pp. 4435-4443.
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Abstract
The mean spherical approxn. (MSA) approach for electrolyte solns. is combined with a modified non-random two-liq. (NRTL) approach. The resulting model is suitable for a description of the thermodn. properties of electrolyte-multisolvent systems. The ability of this MSA-NRTL model is investigated by examg. activity and osmotic coeffs. of binary and ternary electrolyte solns. Esp. for non-aq. solns., the model is superior to std. semi-empirical calcns. used in the chem. industry.
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2002 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz | ||||
| Identification Number: |
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| Keywords: | electrolyte soln thermodn MSA NRTL model | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 24615 |
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