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Dynamics of liquid acetonitrile at high frequencies

Kunz, Werner ; Calmettes, P. ; Bellisent-Funel, M.-C.



Abstract

Quasielastic neutron scattering spectra were measured for pure acetonitrile at 25°C. In the framework of a simple model of translation and rotation, it was found that the short-time self-diffusion coeff. of liq. acetonitrile is similar to the long-time one measured by NMR. As far as the rotational motion is concerned, the characteristic time was found to be close to the typical value of the ...

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