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Dynamics of liquid acetonitrile at high frequencies

Kunz, Werner, Calmettes, P. and Bellisent-Funel, M.-C. (1993) Dynamics of liquid acetonitrile at high frequencies. Journal of Chemical Physics 99 (3), pp. 2079-2082.

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Quasielastic neutron scattering spectra were measured for pure acetonitrile at 25°C. In the framework of a simple model of translation and rotation, it was found that the short-time self-diffusion coeff. of liq. acetonitrile is similar to the long-time one measured by NMR. As far as the rotational motion is concerned, the characteristic time was found to be close to the typical value of the ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
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Keywords:dynamics liq acetonitrile
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24642
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