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Transport of cryptates as model brownons: electrical mobilities and self-diffusion coefficients of monovalent and divalent ions cryptated by 222 in aqueous solutions

Rossy-Delluc, S., Cartailler, T., Turq, P., Bernard, Olivier, Morel-Desrosiers, N., Morel, J.-P. and Kunz, Werner (1993) Transport of cryptates as model brownons: electrical mobilities and self-diffusion coefficients of monovalent and divalent ions cryptated by 222 in aqueous solutions. Journal of Physical Chemistry 97 (19), pp. 5136-5140.

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Abstract

Cryptates present a quasi-spherical symmetry and a practically const. size for a charge varying from 0 (unchanged empty cryptand) to 1 or 2 (cryptand contg. a monovalent or divalent cation). They are therefore sensible models of heavy and large particles undergoing Brownian motion (brownons). Their transport properties in aq. solns., electrophoretic mobilities, and self-diffusion coeffs. are in good agreement with this Brownian dynamical model.


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Item type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1021/j100121a047DOI
Keywords:transport cryptate brownon model self diffusion Brownon motion cryptate brownian model electrophoretic mobility cryptate brownian model
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24644
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