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Transport in electrolytes using the mean spherical approximation: electrical conductance and self-diffusion coefficient as a function of concentration in solutions

Turq, P. ; Bernard, Olivier ; Kunz, Werner ; Blum, L.



Abstract

The Fuose-Onsager continuity equations are solved with a Green's function technique in order to get the laws of variation of transport coeffs. with concn. Any kind of equil. pair correlation function can be used for this purpose, those of the MSA (mean spherical approxn.) leading to explicit expressions for the variation of the self-diffusion coeffs. and of the equiv. conductances with concn. ...

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