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Self-diffusion in electrolyte solutions using the mean spherical approximation

Bernard, Olivier ; Kunz, Werner ; Turq, P. ; Blum, L.


The authors use the equations of the Fuoss-Onsager theory, which are solved by a Green's function technique that yields explicit expressions in terms of the equil. pair correlation functions. The pair correlations needed to obtain these expressions are derived from either the hypernetted chain (HNC) or mean spherical (MSA) approxns. Both yield rather good agreement with available exptl. data ...


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