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Dynamics of water confined in self-assembled monoglyceride-water-oil phases
Wachter, Wolfgang, Trimmel, G.
, Buchner, Richard
und Glatter, Otto
(2011)
Dynamics of water confined in self-assembled monoglyceride-water-oil phases.
Soft Matter 7 (4), S. 1409-1417.
Veröffentlichungsdatum dieses Volltextes: 08 Jun 2012 10:57
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.24715
Zusammenfassung
The dynamics of water confined in various self-assembled liquid-crystalline phases of the system Dimodan U/J-R(+)-limonene-water have been investigated by dielectric relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 <= nu/GHz <= 50). For all phases, two water-related Debye processes were detected, one slightly slower, the other considerably slower, than bulk water. Besides these ...
The dynamics of water confined in various self-assembled liquid-crystalline phases of the system Dimodan U/J-R(+)-limonene-water have been investigated by dielectric relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 <= nu/GHz <= 50). For all phases, two water-related Debye processes were detected, one slightly slower, the other considerably slower, than bulk water. Besides these bulk-like and slow-water relaxations, a further fraction of water does not appear in the dielectric spectra due to strong interactions with the interface (bound water). Increasing the water content of the inverse hexagonal (H-II) phase leads to an increase in both bulk-like and bound water, whereas the amount of slow water remains constant. Furthermore, the bulk-like water relaxation times accelerate until they reach the pure-water value when approaching the saturation line. This finding is supported by differential scanning calorimetry (DSC), which also confirms the presence of three types of water in liquid-crystalline confinement.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Soft Matter | ||||
| Verlag: | ROYAL SOC CHEMISTRY | ||||
|---|---|---|---|---|---|
| Ort der Veröffentlichung: | CAMBRIDGE | ||||
| Band: | 7 | ||||
| Nummer des Zeitschriftenheftes oder des Kapitels: | 4 | ||||
| Seitenbereich: | S. 1409-1417 | ||||
| Datum | 2011 | ||||
| Institutionen | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Chemie IV - Physikalische Chemie (Solution Chemistry) > PD Dr. Richard Buchner | ||||
| Identifikationsnummer |
| ||||
| Stichwörter / Keywords | DRUG-DELIVERY SYSTEMS; LIQUID-CRYSTALLINE PHASES; DIELECTRIC-RELAXATION; ELECTROLYTE-SOLUTIONS; SUBMICRON PARTICLES; SOLVENT RELAXATION; MICROEMULSIONS; DISPERSIONS; BEHAVIOR; SPECTROSCOPY; | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-247156 | ||||
| Dokumenten-ID | 24715 |
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