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Wachter, Wolfgang ; Trimmel, G. ; Buchner, Richard ; Glatter, Otto

Dynamics of water confined in self-assembled monoglyceride-water-oil phases

Wachter, Wolfgang, Trimmel, G. , Buchner, Richard und Glatter, Otto (2011) Dynamics of water confined in self-assembled monoglyceride-water-oil phases. Soft Matter 7 (4), S. 1409-1417.

Veröffentlichungsdatum dieses Volltextes: 08 Jun 2012 10:57
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.24715


Zusammenfassung

The dynamics of water confined in various self-assembled liquid-crystalline phases of the system Dimodan U/J-R(+)-limonene-water have been investigated by dielectric relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 <= nu/GHz <= 50). For all phases, two water-related Debye processes were detected, one slightly slower, the other considerably slower, than bulk water. Besides these ...

The dynamics of water confined in various self-assembled liquid-crystalline phases of the system Dimodan U/J-R(+)-limonene-water have been investigated by dielectric relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 <= nu/GHz <= 50). For all phases, two water-related Debye processes were detected, one slightly slower, the other considerably slower, than bulk water. Besides these bulk-like and slow-water relaxations, a further fraction of water does not appear in the dielectric spectra due to strong interactions with the interface (bound water). Increasing the water content of the inverse hexagonal (H-II) phase leads to an increase in both bulk-like and bound water, whereas the amount of slow water remains constant. Furthermore, the bulk-like water relaxation times accelerate until they reach the pure-water value when approaching the saturation line. This finding is supported by differential scanning calorimetry (DSC), which also confirms the presence of three types of water in liquid-crystalline confinement.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftSoft Matter
Verlag:ROYAL SOC CHEMISTRY
Ort der Veröffentlichung:CAMBRIDGE
Band:7
Nummer des Zeitschriftenheftes oder des Kapitels:4
Seitenbereich:S. 1409-1417
Datum2011
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Lehrstuhl für Chemie IV - Physikalische Chemie (Solution Chemistry) > PD Dr. Richard Buchner
Identifikationsnummer
WertTyp
10.1039/c0sm00681eDOI
Stichwörter / KeywordsDRUG-DELIVERY SYSTEMS; LIQUID-CRYSTALLINE PHASES; DIELECTRIC-RELAXATION; ELECTROLYTE-SOLUTIONS; SUBMICRON PARTICLES; SOLVENT RELAXATION; MICROEMULSIONS; DISPERSIONS; BEHAVIOR; SPECTROSCOPY;
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-247156
Dokumenten-ID24715

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