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Are Nanoscale Ion Aggregates Present in Aqueous Solutions of Guanidinium Salts?

Hunger, J. ; Niedermayer, S. ; Buchner, Richard ; Hefter, Glenn


A detailed investigation using broadband dielec. relaxation spectroscopy (DRS) has been made of the aq. solns. of guanidinium chloride and carbonate, GdmCl(aq) and Gdm2CO3(aq), at 25 °C. The spectra indicate that Gdm+ ions, C(NH2)3+, do not bind strongly to water nor are they hydrophobically hydrated; rather they appear to have a most unusual ability to dissolve in water without altering its ...


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