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Chemical speciation in ionic liquids and their mixtures with polar solvents using dielectric spectroscopy

Hefter, Glenn ; Buchner, Richard ; Hunger, J. ; Stoppa, A.


Broadband dielec. relaxation spectroscopy (DRS) is a powerful tool for studying the nature and dynamics of room-temp. ionic liqs., as well as providing the only means to directly measure their dielec. consts. The DR spectra of neat ionic liqs. exhibit many modes, esp. at high frequencies, where they reflect 'intermol.' vibrations and librations. Detailed investigations have also been made into ...


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