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Modelling fast mode dielectric relaxation of counterions in aqueous solutions of ionene bromides and fluorides

Lukšič, M. ; Hribar-Lee, B. ; Buchner, Richard ; Vlachy, V.


The parameters derived from previously published dielec. spectra of aq. solns. of aliph. 3,3-, 4,5-, 6,6-, and 6,9-ionene bromides and fluorides were analyzed within the existing models for the fast counterion-relaxation process. By fitting the Poisson-Boltzmann results to the exptl. data for the osmotic coeffs. of the ionenes in question, we were able to est. the self-diffusion coeffs. of ...


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