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Dipole Correlations in the Ionic Liquid 1-N-Ethyl-3-N-methylimidazolium Ethylsulfate and Its Binary Mixtures with Dichloromethane

Hunger, J. ; Stoppa, A. ; Buchner, Richard ; Hefter, Glenn


Dielec. spectra over the frequency range of 0.2 .ltorsim. ν/GHz ≤ 89 were measured for the room-temp. ionic liq. 1-N-ethyl-3-N-methylimidazolium ethylsulfate ([emim][EtSO4], IL) and its mixts. with dichloromethane (DCM) at temps. of 5 ≤ .vtheta./°C ≤ 65 and 25° resp. The spectra of the neat IL at all temps. and those of the mixts. could be satisfactorily fitted by assuming three relaxation ...


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