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From Ionic Liquid to Electrolyte Solution: Dynamics of 1-N-Butyl-3-N-methylimidazolium Tetrafluoroborate/Dichloromethane Mixtures

Hunger, J. ; Stoppa, A. ; Buchner, Richard ; Hefter, Glenn


Dielec. spectra have been measured at 25 °C for mixts. of the room temp. ionic liq. 1-N-butyl-3-N-methylimidazolium tetrafluoroborate (IL) with dichloromethane (DCM) over the entire compn. range at frequencies 0.2 .ltorsim. ν/GHz ≤ 89. The spectra could be satisfactorily fitted by assuming only two relaxation modes: a Cole-Cole process at lower frequencies and a Debye process at higher ...


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