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Scandium Sulfate Complexation in Aqueous Solution by Dielectric Relaxation Spectroscopy

Schrödle, S. ; Wachter, Wolfgang ; Buchner, Richard ; Hefter, Glenn



Abstract

Ion assocn. in aq. solns. of scandium sulfate has been investigated at 25 °C and at concns. from 0.01 to 0.8 M by broadband dielec. spectroscopy over the frequency range 0.2 ≤ ν/GHz ≤ 89. Detailed anal. of the spectra reveals the presence of both inner- and outer-sphere 1:1 [ScSO4]+(aq) complexes, similar to solns. of other high-valent metal sulfates. Outer-outer-sphere 1:1 complexes are ...

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