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Intramolecular Charge Transfer Reaction, Polarity, and Dielectric Relaxation in AOT/Water/Heptane Reverse Micelles: Pool Size Dependence

Biswas, Ranjit ; Rohman, Nashiour ; Pradhan, Tuhin ; Buchner, Richard



Abstract

Intramol. charge transfer (ICT) reaction in a newly synthesized mol., of 4-(41-morpholinyl) benzonitrile (M6C), in AOT/water/heptane reverse micelles at different pool sizes has been studied by using steady-state and time-resolved fluorescence emission spectroscopy. The pool size dependences of the reaction equil. const. and reaction rate have been explained in terms of the av. polarity of the ...

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