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Interactions and Dynamics in Ionic Liquids

Stoppa, A. ; Hunger, J. ; Buchner, Richard ; Hefter, Glenn ; Thoman, A. ; Helm, H.



Abstract

Precise dielec. spectra were detd. at 25° over the exceptionally broad frequency range of 0.1 ≤ ν/GHz ≤ 3000 for the imidazolium-based room-temp. ionic liqs. (RTILs) [bmim][BF4], [bmim][PF6], [bmim][DCA], and [hmim][BF4]. The spectra are dominated by a low-frequency process at ∼1 GHz with a broad relaxation time distribution of the Cole-Davidson or Cole-Cole type, which is thought to correspond ...

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