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Glasslike behavior in aqueous electrolyte solutions

Turton, D.A. ; Hunger, J. ; Hefter, Glenn ; Buchner, Richard ; Wynne, K.



Abstract

When salts are added to water, generally the viscosity increases, suggesting that the ions increase the strength of the water's hydrogen-bond network. However, IR pump-probe measurements on electrolyte solns. have found that ions have no influence on the rotational dynamics of water mols., implying no enhancement or breakdown of the hydrogen-bond network. Here, the authors report optical Kerr ...

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