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Ion association and hydration in 3:2 electrolyte solutions by dielectric spectroscopy: aluminum sulfate

Schrödle, S. ; Rudolph, W.W. ; Hefter, Glenn ; Buchner, Richard


Broadband dielec. measurements utilizing state-of-the-art coaxial reflectometry and traveling-wave interferometry have been made on aq. solns. of the 3:2 electrolyte aluminum sulfate at 25° over the frequency range 0.2 ≤ ν (GHz) ≤ 89 and at total solute concns. 0.012 ≤ c (M) ≤ 0.65. Detailed anal. of the solute contribution to the dielec. spectra revealed the simultaneous presence of double ...


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