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Ion association and hydration in aqueous solutions of LiCl and Li2SO4 by dielectric spectroscopy

Wachter, Wolfgang ; Fernandez, Sarka ; Buchner, Richard ; Hefter, Glenn



Abstract

A systematic study of the dielectric relaxation spectra of aqueous solutions of LiCl and Li2SO4 has been made at solute concentrations of 0.05 <= c/ M <= 1.0 and 2.0, respectively, and over a wide range of frequencies (0.2 <= v/GHz <= 89) at 25 degrees C. The spectra were best described by a superposition of four Debye processes, consisting of the two well-known water relaxations at ca. 8 and 0.5 ...

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