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Picosecond dynamics and microheterogenity of water+dioxane mixtures

Schrödle, S. ; Fischer, Bernd ; Helm, H. ; Buchner, Richard


Dielectric spectra from 200 MHz up to 3 THz were determined to study the fast dynamics of dilute water+1,4-dioxane. epsilon(nu) could be fitted by a collision induced oscillator at high frequencies plus two Debye relaxations in the microwave region. Isotope substitution was used to assign water and dioxane modes. The presence of the cooperative hydrogen-bond network relaxation down to a water ...


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