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Poly(ethylene glycol)-conjugated Phospholipids in Aqueous Micellar Solutions: Hydration, Static Structure, and Interparticle Interactions

Sato, T. ; Sakai, H. ; Sou, K. ; Buchner, Richard ; Tsuchida, E.



Abstract

By means of dielec. relaxation spectroscopy (DRS) and small-angle X-ray scattering (SAXS), we have investigated hydration behavior, solvent dynamics, and static structures of aq. solns. of poly(ethylene glycol)-conjugated distearoyl phosphatidylethanolamine (DSPE-PEG) (mol. wt. of PEG: MPEG = 2000, 5000, and 12 000 Da). A quant. anal. of the bulk-water relaxation amplitude revealed the effective ...

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