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Temperature effects on ion association and hydration in MgSO4 by dielectric spectroscopy

Akilan, C. ; Rohman, Nashiour ; Hefter, Glenn ; Buchner, Richard


A detailed investigation of aq. solns. of magnesium sulfate has been made by dielec. relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 ≤ ν/GHz ≤ 89), concns. (0.02 ≤ m/mol kg-1 ≤ 2.3) and temps. (5 ≤ .vtheta./°C ≤ 65). Consistent with literature data from other techniques, the spectra show clear evidence at all temps. for the simultaneous existence of double solvent-sepd. ...


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