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Ion Association and Hydration in Aqueous Solutions of Copper(II) Sulfate from 5 to 65 °C by Dielectric Spectroscopy

Akilan, C. ; Hefter, Glenn ; Rohman, Nashiour ; Buchner, Richard


Aq. solns. of copper(II) sulfate have been studied by dielec. relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 .ltorsim. ν/GHz ≤ 89), concns. (0.02 ≤ m/mol kg-1 .ltorsim. 1.4), and temps. (5 ≤ t/°C ≤ 65). The spectra show clear evidence for the simultaneous existence of double-solvent-sepd., solvent-shared, and contact ion pairs at all temps., with increasing formation esp. of ...


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