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Ion Association and Hydration in Aqueous Solutions of Nickel(II) and Cobalt(II) Sulfate

Chen, T. ; Hefter, Glenn ; Buchner, Richard



Abstract

Aq. solns. of nickel(II) and cobalt(II) sulfate have been investigated at 25 °C by dielec. relaxation spectroscopy (DRS) over a wide range of frequencies (0.2 ≤ ν(GHz) ≤ 89) and salt concns. (0.025 ≤ c(mol-L-1) ≤ 1.4). The spectra indicate, as for MgSO4(aq) studied previously, the simultaneous presence of double solvent-sepd., solvent-shared and contact ion pairs in both NiSO4(aq) and CoSO4(aq). ...

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