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Dielectric Relaxation of Concentrated Alkaline Aluminate Solutions

Buchner, Richard ; Sipos, P. ; Hefter, Glenn ; May, P.M.


The complex dielec. permittivity of concd. aq. alkali aluminate solns. at total concns. 1 .ltorsim. [Al]T/mol dm-3 .ltorsim. 6 with either [Na]T = 8.33 mol dm-3 or [Al]T/[Na]T = 0.750 has been detd. at 25 °C in the frequency range 0.5 .ltorsim. ν/GHz ≤ 20. All soln. spectra could be represented as a superposition of a Cole-Cole relaxation-time distribution for the solvent relaxation with an ...


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