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La[Fe(CN)6] ion pairing in aqueous solution. A dielectric relaxation study

Buchner, Richard ; Barthel, Josef ; Gill, J. B.


Complex permittivity spectra of aq. La[Fe(CN)6] solns. at 25° over the frequency range 0.2 ≤ ν ≤ 89 GHz are presented. Because of the large assocn. const. of La ferricyanide, KA = 5300, and its high ion-pair dipole moment, μIP = 77.7 D, dil. solns. in the range 0.0026≤c/mol dm-3≤0.0485 could be studied. The current models for the anal. of the ion-pair dispersion amplitude are reliable. The ...


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