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Far-infrared studies of the molecular dynamics and interactions in N-methyl formamide

Buchner, Richard ; Yarwood, J.


The effect of diln. in carbon tetrachloride on the far-IR spectra (5-150 cm-1) of N-Me formamide (NMF) was investigated over the whole miscibility range. The data were combined with (literature) microwave data to enable total dipole d. correlation functions to be computed. These emphasize any differences in short time dynamics which occur due to the breaking of hydrogen-bonds with diln. The ...


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