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Spectroscopic studies of solute-solute and solute-solvent interactions in solutions containing N,N-dimethylformamide

Shelley, V. M. ; Talintyre, A. ; Yarwood, J. ; Buchner, Richard


IR, far-IR and Raman spectra of DMF are reported for the liq. and over the whole concn. range in CCl4 soln. The data reflect important differences between the long-ranged and short-ranged behavior of the solute-solute and solute-solvent intermol. potentials. In particular, the far-IR spectrum is dominated by short-ranged interactions which vary only marginally with concn. and which are probably ...


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