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FT-far-infrared spectroscopic studies of solute-solvent interactions and molecular dynamics in solutions of methanol, N-methylformamide and N,N-dimethylformamide

Buchner, Richard ; Yarwood, J.


Quant. measurements of the optical consts. (4-170 cm-1) of 3 org. liqs. and their dil. solns. in CCl4 are interpreted in terms of mol. relaxation processes arising from solute-solute and solute-solvent interactions. The behavior of MeOH and HCONHMe on diln. is quite different from that of DMF, emphasizing the importance of H-bonding potentials in the former two liqs.

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