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Kinetic processes in electrolyte solutions in high frequency electric fields

Barthel, Josef, Bachhuber, K. and Buchner, Richard (1988) Kinetic processes in electrolyte solutions in high frequency electric fields. In: Moreau, M. and Turq, P., (eds.) Chemical Reactivity in liquids : Fundamental aspects ; Proc. (42. Internat. Meeting of the Société Française de Chimie, Div. of Chimie Physique ; Paris, 1987.09.07-11). Plenum, pp. 55-71.

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High frequency permittivity measurements (1-40 GHz) are analyzed to yield information on kinetic processes in aq. and nonaq. electrolyte solns. Information is obtained on the low and high frequency relaxation times of the solvent and their shifts by addn. of electrolytes, rotational relaxation times of ion pairs, assocn. consts., rate consts. of ion-pair formation and decompn., and kinetic depolarization. Examples are given for each process.

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Item type:Book section
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Keywords:electrolyte soln elec field kinetic process
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:24895
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