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Single-Molecule Synthesis and Characterization of Metal−Ligand Complexes by Low-Temperature STM

Liljeroth, Peter ; Swart, Ingmar ; Paavilainen, Sami ; Repp, Jascha ; Meyer, Gerhard



Zusammenfassung

We present scanning tunneling microscopy (STM)-based single-molecule synthesis of linear metal-ligand complexes starting from individual metal atoms (iron or nickel) and organic molecules (9,10-dicyanoanthracene) deposited on an ultrathin insulating film We directly visualize the frontier molecular orbitals by STM orbital imaging, from which, in conjunction with detailed density functional theory ...

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