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Current-Induced Hydrogen Tautomerization and Conductance Switching of Naphthalocyanine Molecules

Liljeroth, Peter ; Repp, Jascha ; Meyer, Gerhard



Abstract

The bistability in the position of the two hydrogen atoms in the inner cavity of single free-base naphthalocyanine molecules constitutes a two-level system that was manipulated and probed by low-temperature scanning tunneling microscopy. When adsorbed on an ultrathin insulating film, the molecules can be switched in a controlled fashion between the two states by excitation induced by the ...

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