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Imaging Bond Formation Between a Gold Atom and Pentacene on an Insulating Surface

Repp, Jascha ; Meyer, Gerhard ; Paavilainen, Sami ; Olsson, Fredrik E. ; Persson, Mats


A covalent bond between an individual pentacene molecule and a gold atom was formed by means of single-molecule chemistry inside a scanning tunneling microscope junction. The bond formation is reversible, and different structural isomers can be produced. The single-molecule synthesis was done on ultrathin insulating films that electronically isolated the reactants and products from their ...


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