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Multipurpose box- and azabox-Based Immobilized Chiral Catalysts

Fraile, José M., Pérez, Ignacio, Mayoral, José A. and Reiser, Oliver (2006) Multipurpose box- and azabox-Based Immobilized Chiral Catalysts. Advanced Synthesis & Catalysis 348 (12-13), pp. 1680-1688.

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Azabis(oxazolines) can be used as chiral ligands in the copper-catalyzed enantioselective Mukaiyama aldol reaction. When supported on solids, azabis(oxazoline)-copper complexes are more easily deactivated than their analogous bis(oxazoline)- copper complexes, and are not compatible with the use of coordinating solvents in the method of preparation. The performance of the immobilized catalysts (up ...


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Item type:Article
Date:August 2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Keywords:asymmetric catalysis; azabis(oxazolines); cyclopropanation; Mukaiyama aldol; supported catalysts
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:2528
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