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Modular synthesis of chiral pentadentate bis(oxazoline) ligands

Seitz, Michael, Kaiser, Anja, Tereshchenko, Alexander, Geiger, Christian, Uematsu, Yukitaka and Reiser, Oliver (2006) Modular synthesis of chiral pentadentate bis(oxazoline) ligands. Tetrahedron 62 (42), pp. 9973-9980.

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Highly modular N,Y,Z,Y,N-ligands (Y=N, O, S; Z=N, NO, OH, OMe) have been prepared using bis(oxazoline) building blocks either as nucleophiles or as electrophiles in coupling reactions with central aromatic units. This way, a great variety of pentadentate bis(oxazoline) ligands in diastereo- and enantiomerically pure form become readily available, which are useful for the construction of helical metal complexes with predetermined chirality.

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Item type:Article
Date:16 October 2006
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:2529
Owner only: item control page


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