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Modular synthesis of chiral pentadentate bis(oxazoline) ligands
Seitz, Michael, Kaiser, Anja, Tereshchenko, Alexander, Geiger, Christian, Uematsu, Yukitaka and Reiser, Oliver
(2006)
Modular synthesis of chiral pentadentate bis(oxazoline) ligands.
Tetrahedron 62 (42), pp. 9973-9980.
Date of publication of this fulltext: 05 Aug 2009 13:40
Article
DOI to cite this document: 10.5283/epub.2529
Abstract
Highly modular N,Y,Z,Y,N-ligands (Y=N, O, S; Z=N, NO, OH, OMe) have been prepared using bis(oxazoline) building blocks either as nucleophiles or as electrophiles in coupling reactions with central aromatic units. This way, a great variety of pentadentate bis(oxazoline) ligands in diastereo- and enantiomerically pure form become readily available, which are useful for the construction of helical metal complexes with predetermined chirality. (c) 2006 Elsevier Ltd. All rights reserved.
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| Item type | Article | ||||
| Journal or Publication Title | Tetrahedron | ||||
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
|---|---|---|---|---|---|
| Place of Publication: | OXFORD | ||||
| Volume: | 62 | ||||
| Number of Issue or Book Chapter: | 42 | ||||
| Page Range: | pp. 9973-9980 | ||||
| Date | 16 October 2006 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser | ||||
| Identification Number |
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| Keywords | JM-PHOS LIGANDS; ASYMMETRIC CATALYSIS; OXAZOLINE LIGANDS; COPPER(II) COMPLEXES; ALLYLIC ALKYLATIONS; HELICAL CHIRALITY; CRYSTAL-STRUCTURE; HYDROGENATION; KETONES; DESIGN; | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| Item ID | 2529 |
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