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Regioselective Complexation of 1,2:9,10-Dibenzo[2.2]paracyclophanedienes

Reiser, Oliver and Meijere, Armin de (1991) Regioselective Complexation of 1,2:9,10-Dibenzo[2.2]paracyclophanedienes. Journal of Organometallic Chemistry 413 (1-3), pp. 137-141.

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Other URL: http://dx.doi.org/10.1016/0022-328X(91)80044-K


1,2:9,10-Dibenzo[2.2]paracyclophane-1,9-diene, 1, and its 4′,5′,4″,5″-tetrakis(p-t-butylphenyl) derivative, 2b, regioselectively from the tricarbonylchromium(0) complexes 3, 5 and 4, 6, respectively, in which the (CO)₃Cr units are attached to the phane arene units. This is manifestation of the increased π-basicities of their bent arene moieties; surprisingly even the second (CO)₃Cr unit prefers the bent arene in spite of the electron withdrawing effect of the first one.

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Item type:Article
Date:7 August 1991
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:259
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