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Chromophores in Conjugated Polymers—All Straight?

Lupton, John M. (2012) Chromophores in Conjugated Polymers—All Straight? ChemPhysChem 13 (4), pp. 901-907.

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Abstract

What is the physical shape of the π-electron system in a large macromolecule such as a conjugated polymer? Although intuitively one may argue that any departure from rigidity by bending or twisting should disrupt conjugation, leading to the formation of discrete chromophores, single-molecule and ensemble time-resolved studies support the notion that the π-bond is remarkably persistent in space: ...

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Item type:Article
Date:March 2012
Institutions:Physics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group John Lupton
Identification Number:
ValueType
10.1002/cphc.201100770DOI
Related URLs:
URLURL Type
http://onlinelibrary.wiley.com/doi/10.1002/cphc.201100770/abstractPublisher
Keywords:SINGLE-MOLECULE SPECTROSCOPY; ENERGY-TRANSFER; CHAIN CONFORMATION; LOW-TEMPERATURE; MORPHOLOGY; FLUORESCENCE; RELAXATION; EXCITONS; LOCALIZATION; LUMINESCENCE
Dewey Decimal Classification:500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:26705
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