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Baker, W. J. ; McCamey, D. R. ; van Schooten, K. J. ; Lupton, J. M. ;

Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating

Baker, W. J., McCamey, D. R. , van Schooten, K. J., Lupton, J. M. und make_name_string expected hash reference (2011) Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating. Physical Review B (PRB) 84 (16), S. 165205.

Veröffentlichungsdatum dieses Volltextes: 15 Nov 2012 08:21
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.26708


Zusammenfassung

Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes ...

Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes simultaneously impact the device conductivity. The two mechanisms are distinguished by the presence of a half-field resonance, indicative of TEP interactions, and transient spin beating, the signature of PPs. Coherent spin Rabi flopping in the half-field (triplet) channel is observed, demonstrating that the triplet exciton has an ensemble phase coherence time of at least 60 ns, offering insight into the effect of carrier correlations on spin dephasing.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftPhysical Review B (PRB)
Verlag:AMER PHYSICAL SOC
Ort der Veröffentlichung:COLLEGE PK
Band:84
Nummer des Zeitschriftenheftes oder des Kapitels:16
Seitenbereich:S. 165205
Datum19 Oktober 2011
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Lupton > Arbeitsgruppe John Lupton
Identifikationsnummer
WertTyp
10.1103/PhysRevB.84.165205DOI
Klassifikation
NotationArt
71.20.RvPACS
71.35.GgPACS
Stichwörter / KeywordsPI-CONJUGATED POLYMERS; SEMICONDUCTORS; PHOTOGENERATION; RECOMBINATION; SINGLET; FILMS;
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenZum Teil
URN der UB Regensburgurn:nbn:de:bvb:355-epub-267086
Dokumenten-ID26708

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