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Baker, W. J. ; McCamey, D. R. ; van Schooten, K. J. ; Lupton, J. M. ;

Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating

Baker, W. J., McCamey, D. R. , van Schooten, K. J., Lupton, J. M. and make_name_string expected hash reference (2011) Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating. Physical Review B (PRB) 84 (16), p. 165205.

Date of publication of this fulltext: 15 Nov 2012 08:21
Article
DOI to cite this document: 10.5283/epub.26708


Abstract

Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes ...

Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes simultaneously impact the device conductivity. The two mechanisms are distinguished by the presence of a half-field resonance, indicative of TEP interactions, and transient spin beating, the signature of PPs. Coherent spin Rabi flopping in the half-field (triplet) channel is observed, demonstrating that the triplet exciton has an ensemble phase coherence time of at least 60 ns, offering insight into the effect of carrier correlations on spin dephasing.



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Details

Item typeArticle
Journal or Publication TitlePhysical Review B (PRB)
Publisher:AMER PHYSICAL SOC
Place of Publication:COLLEGE PK
Volume:84
Number of Issue or Book Chapter:16
Page Range:p. 165205
Date19 October 2011
InstitutionsPhysics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group John Lupton
Identification Number
ValueType
10.1103/PhysRevB.84.165205DOI
Classification
NotationType
71.20.RvPACS
71.35.GgPACS
KeywordsPI-CONJUGATED POLYMERS; SEMICONDUCTORS; PHOTOGENERATION; RECOMBINATION; SINGLET; FILMS;
Dewey Decimal Classification500 Science > 530 Physics
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgPartially
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-267086
Item ID26708

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