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Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating
Baker, W. J., McCamey, D. R.
, van Schooten, K. J., Lupton, J. M. and make_name_string expected hash reference
(2011)
Differentiation between polaron-pair and triplet-exciton polaron spin-dependent mechanisms in organic light-emitting diodes by coherent spin beating.
Physical Review B (PRB) 84 (16), p. 165205.
Date of publication of this fulltext: 15 Nov 2012 08:21
Article
DOI to cite this document: 10.5283/epub.26708
Abstract
Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes ...
Pulsed electrically detected magnetic resonance offers a unique avenue to distinguish between polaron-pair (PP) and triplet-exciton polaron (TEP) spin-dependent recombination, which control the conductivity and magnetoresistivity of organic semiconductors. Which of these two fundamental processes dominates depends on carrier balance: by injecting surplus electrons we show that both processes simultaneously impact the device conductivity. The two mechanisms are distinguished by the presence of a half-field resonance, indicative of TEP interactions, and transient spin beating, the signature of PPs. Coherent spin Rabi flopping in the half-field (triplet) channel is observed, demonstrating that the triplet exciton has an ensemble phase coherence time of at least 60 ns, offering insight into the effect of carrier correlations on spin dephasing.
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| Item type | Article | ||||||
| Journal or Publication Title | Physical Review B (PRB) | ||||||
| Publisher: | AMER PHYSICAL SOC | ||||||
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| Place of Publication: | COLLEGE PK | ||||||
| Volume: | 84 | ||||||
| Number of Issue or Book Chapter: | 16 | ||||||
| Page Range: | p. 165205 | ||||||
| Date | 19 October 2011 | ||||||
| Institutions | Physics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group John Lupton | ||||||
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| Classification |
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| Keywords | PI-CONJUGATED POLYMERS; SEMICONDUCTORS; PHOTOGENERATION; RECOMBINATION; SINGLET; FILMS; | ||||||
| Dewey Decimal Classification | 500 Science > 530 Physics | ||||||
| Status | Published | ||||||
| Refereed | Yes, this version has been refereed | ||||||
| Created at the University of Regensburg | Partially | ||||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-267086 | ||||||
| Item ID | 26708 |
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