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Aggregation Effects in Visible-Light Flavin Photocatalysts: Synthesis, Structure, and Catalytic Activity of 10-Arylflavins

Dadova, Jitka ; Kümmel, Susanne ; Feldmeier, Christian ; Cibulkova, Jana ; Pazout, Richard ; Maixner, Jaroslav ; Gschwind, Ruth M. ; König, Burkhard ; Cibulka, Radek


A series of 10-arylflavins (10-phenyl-, 10-(2',6'-dimethylphenyl)-, 10-(2',6'-diethylphenyl)-, 10-(2',6'-diisopropylphenyl)-, 10-(2'-tert-butylphenyl)-, and 10-(2',6'-dimethylphenyl)-3-methylisoalloxazine (2 a-f)) was prepared as potentially nonaggregating flavin photocatalysts. The investigation of their structures in the crystalline phase combined with (1) H-DOSY NMR spectroscopic experiments ...


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