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Organic reactivity of alcohols in superheated aqueous salt solutions: an overview

Avola, Sabine ; Goettmann, Frédéric ; Antonietti, Markus ; Kunz, Werner


The low dielec. const. and high self-dissocn. const. of water in a temp. range between 150 and 250 °C make it a very appealing solvent for synthesis. Surprisingly, while org. chem. in water at low temp. or around its crit. point has been investigated in detail, very little seems to be known about the behavior of org. mols. under hydrothermal conditions. The present work thus aims at shedding ...


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