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A Conductance Study of Guanidinium Chloride, Thiocyanate, Sulfate, and Carbonate in Dilute Aqueous Solutions: Ion-Association and Carbonate Hydrolysis Effects

Hunger, Johannes ; Neueder, Roland ; Buchner, Richard ; Apelblat, A.



Abstract

We study the conductance of dil. aq. solns. for a series of guandinium salts at 298.15 K. The exptl. molar conductivities were analyzed within the framework of the Quint-Viallard theory in combination with Debye-Hueckel activity coeffs. From this anal., we find no evidence for significant ion assocn. in aq. solns. of guanidinium chloride (GdmCl) and guanidinium thiocyanate (GdmSCN), and the ...

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