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A Conductance Study of Guanidinium Chloride, Thiocyanate, Sulfate, and Carbonate in Dilute Aqueous Solutions: Ion-Association and Carbonate Hydrolysis Effects

Hunger, Johannes, Neueder, Roland, Buchner, Richard and Apelblat, A. (2013) A Conductance Study of Guanidinium Chloride, Thiocyanate, Sulfate, and Carbonate in Dilute Aqueous Solutions: Ion-Association and Carbonate Hydrolysis Effects. Journal of Physical Chemistry B 117 (2), pp. 615-622.

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Abstract

We study the conductance of dil. aq. solns. for a series of guandinium salts at 298.15 K. The exptl. molar conductivities were analyzed within the framework of the Quint-Viallard theory in combination with Debye-Hueckel activity coeffs. From this anal., we find no evidence for significant ion assocn. in aq. solns. of guanidinium chloride (GdmCl) and guanidinium thiocyanate (GdmSCN), and the ...

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Item type:Article
Date:2013
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1021/jp311425vDOI
Keywords:conductance guanidinium chloride thiocyanate sulfate carbonate dil aq soln
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:27397
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