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The Supramolecular Balance for Transition-Metal Complexes: Assessment of Noncovalent Interactions in Phosphoramidite Palladium Complexes.

Hartmann, Evelyn ; Gschwind, Ruth Maria



Abstract

The virtue of enantiomers: A general method has been developed for measuring the individual contributions of noncovalent interactions within transition-metal complexes and dissecting them from electronic effects. On Pd complexes with one enantiopure and two enantiomeric phosphoramidite ligands it was experimentally shown that modulations in extended CH-� and


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