Controlling the Orbital Sequence in Individual Cu-Phthalocyanine Molecules

Uhlmann, Christof ; Swart, Ingmar ; Repp, Jascha

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Veröffentlichungsdatum dieses Volltextes: 08 Feb 2013 06:47

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We report on the controlled change of the energetic ordering of molecular orbitals. Negatively charged copper(II)phthalocyanine on NaCl/Cu(100) undergoes a Jahn−Teller distortion that lifts the degeneracy of two frontier orbitals. The energetic order of the levels can be controlled by Au and Ag atoms in the vicinity of the molecule. As only one of the states is occupied, the control of the ...